Kinetic Parameters for the Selective Hydrogenation of Acetylene on GaPd 2 and GaPd

Intermetallic GaPd 2 is a highly selective and stable catalyst for the semi‐hydrogenation of acetylene. Knowledge of the underlying reaction kinetics is essential to gain a deeper understanding of the selective hydrogenation on this catalytic material. To date, there has been no experimental kinetic data published for this reaction on a well‐defined intermetallic catalyst possessing isolated active sites. Kinetic measurements are performed at 140–200 °C, revealing an apparent activation energy of 29(2) kJ mol −1 . GaPd 2 is shown to be the first binary catalyst material, which shows a positive reaction order (0.89) with respect to acetylene at 200 °C. The influences on the extent of acetylene conversion, specific activity and selectivity to ethylene, ethane, and higher hydrocarbons are determined by a 2 4 factorial experiment following a design of experiments approach. Temperature and pressure have the strongest impact on these values. The results allow optimal operation for achieving high ethylene yields. A comparison of the reaction kinetics on GaPd 2 with experimental results obtained for GaPd reveals different orders of reaction of H 2 and C 2 H 2 on the two compounds.