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A Highly Stable Nonhysteretic {Cu 2 (tebpz) MOF+water} Molecular Spring
Author(s) -
Grosu Yaroslav,
Li Mian,
Peng YunLei,
Luo Dong,
Li Dan,
Faik Abdessamad,
Nedelec JeanMarie,
Grolier JeanPierre
Publication year - 2016
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201600567
Subject(s) - nanoporous , thermal stability , spring (device) , thermal , metal organic framework , materials science , molecular dynamics , chemical engineering , chemical physics , nanotechnology , chemistry , thermodynamics , computational chemistry , organic chemistry , physics , adsorption , engineering
A molecular spring formed by a hydrophobic metal–organic framework Cu 2 (tebpz) (tebpz=3,3′,5,5′‐tetraethyl‐4,4′‐bipyrazolate) and water is presented. This nanoporous heterogeneous lyophobic system (HLS) has exceptional properties compared to numerous reported systems of such type in terms of stability, efficiency, and operating pressure. Mechanical and thermal energetic characteristics as well as stability of the system are discussed and compared in detail with those of other previously reported HLS.