Kamlet–Taft Solvation Parameters of Solvate Ionic Liquids | Zendy

Dolan Dr Andrew | Zendy; Sherman Dylan A. | Zendy; Atkin Rob | Zendy; Warr Gregory G. | Zendy

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Kamlet–Taft Solvation Parameters of Solvate Ionic Liquids

Author(s) -

Dolan Dr Andrew,

Sherman Dylan A.,

Atkin Rob,

Warr Gregory G.

Publication year - 2016

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201600361

Subject(s) - chemistry , ionic liquid , solvation , lithium (medication) , salt (chemistry) , solvent , solvatochromism , ionic bonding , inorganic chemistry , ion , organic chemistry , catalysis , medicine , endocrinology

The Kamlet–Taft solvent parameters of solvate ionic liquids (SILs) prepared from lithium salts with glyme and glycol ligands are determined. The dipolarity/polarisibilities (π*) are high, similar to those found in conventional ionic liquids. The H‐bond basicities ( β ) depend strongly on the anion. The H‐bond acidities ( α ) are high in both glyme and glycol SILs, indicating that the lithium is acting as a H‐bond donor site. “Poor” SILs have glyme‐rich and salt‐rich regions. In these liquids the π* and β values are almost identical to the parent glyme or glycol, and the α values are determined by the salt alone.

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