Premium
Interpretation of Spectroscopic Markers of Hydrogen Bonds
Author(s) -
Scheiner Steve
Publication year - 2016
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201600326
Subject(s) - chemistry , proton , hydrogen bond , acceptor , molecule , hydrogen atom , crystallography , chemical shift , electromagnetic shielding , density functional theory , proton nmr , low barrier hydrogen bond , electron density , computational chemistry , photochemistry , chemical physics , electron , group (periodic table) , stereochemistry , physics , organic chemistry , quantum mechanics
Quantum calculations are used to examine whether an AH⋅⋅⋅D H‐bond is unambiguously verified by a downfield shift of the bridging proton's NMR signal or a red (or blue) shift of the AH stretching frequency in the IR spectrum. It is found that such IR band shifts will occur even if the two groups experience weak or no attractive force, or if they are drawn in so close together that their interaction is heavily repulsive. The mere presence of a proton‐acceptor molecule can affect the chemical shielding of a position occupied by a protondonor by virtue of its electron density, even if there is no H‐bond present. This density‐induced shielding is heavily dependent on position around the proton–acceptor atom, and varies from one group to another. Evidence of a hydrogen bond rests on the measurement of a proton deshielding in excess of what is caused purely by the presence of the proton acceptor species.