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Detection of the Elusive Triazane Molecule (N 3 H 5 ) in the Gas Phase
Author(s) -
Förstel Marko,
Maksyutenko Pavlo,
Jones Brant M.,
Sun BingJian,
Chen ShihHua,
Chang Agnes. H.H.,
Kaiser Ralf I.
Publication year - 2015
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201500560
Subject(s) - sublimation (psychology) , chemistry , nitrogen , molecule , mass spectrometry , ammonia , deuterium , reflectron , analytical chemistry (journal) , ionization , time of flight mass spectrometry , atomic physics , ion , organic chemistry , psychology , physics , chromatography , psychotherapist
We report the detection of triazane (N 3 H 5 ) in the gas phase. Triazane is a higher order nitrogen hydride of ammonia (NH 3 ) and hydrazine (N 2 H 4 ) of fundamental importance for the understanding of the stability of single‐bonded chains of nitrogen atoms and a potential key intermediate in hydrogen–nitrogen chemistry. The experimental results along with electronic‐structure calculations reveal that triazane presents a stable molecule with a nitrogen–nitrogen bond length that is a few picometers shorter than that of hydrazine and has a lifetime exceeding 6±2 μs at a sublimation temperature of 170 K. Triazane was synthesized through irradiation of ammonia ice with energetic electrons and was detected in the gas phase upon sublimation of the ice through soft vacuum ultraviolet (VUV) photoionization coupled with a reflectron‐time‐of‐flight mass spectrometer. Isotopic substitution experiments exploiting [D 3 ]‐ammonia ice confirmed the identification through the detection of its fully deuterated counterpart [D 5 ]‐triazane (N 3 D 5 ).