Entropic Separations of Mixtures of Aromatics by Selective Face‐to‐Face Molecular Stacking in One‐Dimensional Channels of Metal–Organic Frameworks and Zeolites | Zendy

TorresKnoop Ariana | Zendy; Balestra Salvador R. G. | Zendy; Krishna Rajamani | Zendy; Calero Sofía | Zendy; Dubbeldam David | Zendy

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Entropic Separations of Mixtures of Aromatics by Selective Face‐to‐Face Molecular Stacking in One‐Dimensional Channels of Metal–Organic Frameworks and Zeolites

Author(s) -

TorresKnoop Ariana,

Balestra Salvador R. G.,

Krishna Rajamani,

Calero Sofía,

Dubbeldam David

Publication year - 2015

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201402819

Subject(s) - stacking , chemistry , metal organic framework , metal , chemical physics , entropy (arrow of time) , nanotechnology , chemical engineering , materials science , organic chemistry , thermodynamics , adsorption , physics , engineering

Separation of challenging mixtures using metal–organic frameworks can be achieved by an entropy‐driven mechanism, where one of the components can arrange into a “face‐to‐face” stacking, thus reducing its “footprint” and reaching a higher saturation loading.

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