Selective Aerobic Oxidation of Primary Alcohols to Aldehydes over Nb 2 O 5  Photocatalyst with Visible Light | Zendy

Furukawa Shinya | Zendy; Shishido Tetsuya | Zendy; Teramura Kentaro | Zendy; Tanaka Tsunehiro | Zendy

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Selective Aerobic Oxidation of Primary Alcohols to Aldehydes over Nb 2 O 5 Photocatalyst with Visible Light

Author(s) -

Furukawa Shinya,

Shishido Tetsuya,

Teramura Kentaro,

Tanaka Tsunehiro

Publication year - 2014

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201402343

Subject(s) - visible spectrum , photocatalysis , alcohol oxidation , photochemistry , primary (astronomy) , alcohol , irradiation , chemistry , primary alcohol , aldehyde , catalysis , organic chemistry , materials science , optoelectronics , physics , astronomy , nuclear physics

Primary alcohols are selectively converted into aldehydes by using a Nb 2 O 5 photocatalyst under visible‐light irradiation. A strong interaction between the alcohol and Nb 2 O 5 generates a donor level within the forbidden band of Nb 2 O 5 , which provides a visible‐light‐harvesting ability. Over oxidation of aldehydes into carboxylic acids does not proceed under visible‐light irradiation.

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