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Inside Cover: All‐Metal Clusters that Mimic the Chemistry of Halogens (ChemPhysChem 14/2013)
Author(s) -
Zhao Tianshan,
Li Yawei,
Wang Qian,
Jena Puru
Publication year - 2013
Publication title -
chemphyschem
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201390067
Subject(s) - halogen , chemistry , cover (algebra) , metal , ligand (biochemistry) , atom (system on chip) , crystallography , computational chemistry , inorganic chemistry , nanotechnology , materials science , organic chemistry , mechanical engineering , biochemistry , alkyl , receptor , engineering , computer science , embedded system
Au can behave like H in forming super‐ and hyperhalogens with Au acting either as a ligand or as a central atom. Similar to AlH 4 and HF 2 , AlAu 4 and AuF 2 are superhalogens. They can also form hyperhalogens, such as Na(AlAu 4 ) 2 and AuF 2 AuAuF 2 , as shown on p. 3227 by Q. Wang et al.