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Poly(ethylene glycol) Stabilized Mesoporous Metal–Organic Framework Nanocrystals: Efficient and Durable Catalysts for the Oxidation of Benzyl Alcohol
Author(s) -
Xue Zhimin,
Zhang Jianling,
Peng Li,
Han Buxing,
Mu Tiancheng,
Li Jianshen,
Yang Guanying
Publication year - 2014
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201300809
Subject(s) - benzyl alcohol , alcohol oxidation , nanocrystal , mesoporous material , ethylene glycol , fabrication , catalysis , aldehyde , materials science , metal organic framework , vinyl alcohol , porosity , chemical engineering , nanotechnology , combinatorial chemistry , chemistry , organic chemistry , adsorption , medicine , polymer , alternative medicine , pathology , engineering
Active, selective, and stable: The fabrication of uniform mesoporous Cu 3 (BTC) 2 (BTC: 1,3,5‐benzenetricarboxylate) nanocrystals with tunable size and porosity is reported. The as‐synthesized Cu 3 (BTC) 2 structures show high activity, selectivity, and stability for the aerobic oxidation of benzyl alcohol to aldehyde.