Premium
Interplay between Metal⋅⋅⋅π Interactions and Hydrogen Bonds: Some Unusual Synergetic Effects of Coinage Metals and Substituents
Author(s) -
Gao Meng,
Yang Xin,
Cheng Jianbo,
Li Qingzhong,
Li Wenzuo,
Loffredo Robert E.
Publication year - 2013
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201300558
Subject(s) - cooperativity , chemistry , hydrogen bond , ternary operation , metal , crystallography , lewis acids and bases , hydrogen , interaction energy , inorganic chemistry , molecule , organic chemistry , catalysis , biochemistry , computer science , programming language
The ternary systems of C 2 H 4 (C 2 H 2 or C 6 H 6 )‐MCN‐HF (M=Cu, Ag, Au) and the respective binary systems were investigated to study the interplay between metal⋅⋅⋅π interactions and hydrogen bonds. The metal⋅⋅⋅π interactions in C 2 H 4 ‐MCN become stronger with the irregular order Ag