Interplay between Metal⋅⋅⋅π Interactions and Hydrogen Bonds: Some Unusual Synergetic Effects of Coinage Metals and Substituents | Zendy

Gao Meng | Zendy; Yang Xin | Zendy; Cheng Jianbo | Zendy; Li Qingzhong | Zendy; Li Wenzuo | Zendy; Loffredo Robert E. | Zendy

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Interplay between Metal⋅⋅⋅π Interactions and Hydrogen Bonds: Some Unusual Synergetic Effects of Coinage Metals and Substituents

Author(s) -

Gao Meng,

Yang Xin,

Cheng Jianbo,

Li Qingzhong,

Li Wenzuo,

Loffredo Robert E.

Publication year - 2013

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201300558

Subject(s) - cooperativity , chemistry , hydrogen bond , ternary operation , metal , crystallography , lewis acids and bases , hydrogen , interaction energy , inorganic chemistry , molecule , organic chemistry , catalysis , biochemistry , computer science , programming language

The ternary systems of C 2 H 4 (C 2 H 2 or C 6 H 6 )‐MCN‐HF (M=Cu, Ag, Au) and the respective binary systems were investigated to study the interplay between metal⋅⋅⋅π interactions and hydrogen bonds. The metal⋅⋅⋅π interactions in C 2 H 4 ‐MCN become stronger with the irregular order Ag

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