Premium
Viscosity Mixing Rules for Binary Systems Containing One Ionic Liquid
Author(s) -
Tariq Mohammed,
Altamash Tausif,
Salavera Daniel,
Coronas Alberto,
Rebelo Luis P. N.,
Lopes Jose N. Cagia
Publication year - 2013
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201300086
Subject(s) - viscosity , ionic liquid , mixing (physics) , binary number , thermodynamics , relative viscosity , work (physics) , chemistry , solvent , ionic bonding , absolute deviation , mathematics , physics , organic chemistry , ion , statistics , arithmetic , quantum mechanics , catalysis
In this work the applicability of four of the most commonly used viscosity mixing rules to [ionic liquid (IL)+molecular solvent (MS)] systems is assessed. More than one hundred (IL+MS) binary mixtures were selected from the literature to test the viscosity mixing rules proposed by 1) Hind (Hi), 2) Grunberg and Nissan (G–N), 3) Herric (He) and 4) Katti and Chaudhri (K–C). The analyses were performed by estimating the average (absolute or relative) deviations, AADs and ARDs, between the available experimental data and the predicted ideal mixture viscosity values obtained by means of each rule. The interaction terms corresponding to the adjustable parameters inherent to each rule were also calculated and their trends discussed.