Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of Sb V : Electronic and Steric Factors | Zendy

Fukin Georgy K. | Zendy; Baranov Evgenii V. | Zendy; Poddel'sky Andrey I. | Zendy; Cherkasov Vladimir K. | Zendy; Abakumov Gleb A. | Zendy

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Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of Sb V : Electronic and Steric Factors

Author(s) -

Fukin Georgy K.,

Baranov Evgenii V.,

Poddel'sky Andrey I.,

Cherkasov Vladimir K.,

Abakumov Gleb A.

Publication year - 2012

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201200728

Subject(s) - steric effects , reactivity (psychology) , chemistry , electronic effect , oxygen , electronic structure , steric factor , computational chemistry , molecular oxygen , molecule , binding energy , photochemistry , stereochemistry , organic chemistry , atomic physics , medicine , physics , alternative medicine , pathology

Edge of reactivity: The reactions of reversible binding of molecular oxygen to catecholate and amidophenolate complexes of Sb V are investigated by analyzing the position of electronic ( E HOMO ) and steric ( G ‐parameter) factors. The optimal electronic and steric parameters for such type reactions are found.

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