Premium
Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of Sb V : Electronic and Steric Factors
Author(s) -
Fukin Georgy K.,
Baranov Evgenii V.,
Poddel'sky Andrey I.,
Cherkasov Vladimir K.,
Abakumov Gleb A.
Publication year - 2012
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201200728
Subject(s) - steric effects , reactivity (psychology) , chemistry , electronic effect , oxygen , electronic structure , steric factor , computational chemistry , molecular oxygen , molecule , binding energy , photochemistry , stereochemistry , organic chemistry , atomic physics , medicine , physics , alternative medicine , pathology
Edge of reactivity: The reactions of reversible binding of molecular oxygen to catecholate and amidophenolate complexes of Sb V are investigated by analyzing the position of electronic ( E HOMO ) and steric ( G ‐parameter) factors. The optimal electronic and steric parameters for such type reactions are found.