The Chemical Bond in Carbonyl and Sulfinyl Groups Studied by Soft X‐ray Spectroscopy and ab Initio Calculations | Zendy

Atak Kaan | Zendy; Engel Nicholas | Zendy; Lange Kathrin M. | Zendy; Golnak Ronny | Zendy; Gotz Malte | Zendy; Soldatov Mikhail | Zendy; Rubensson JanErik | Zendy; Kosugi Nobuhiro | Zendy; Aziz Emad F. | Zendy

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The Chemical Bond in Carbonyl and Sulfinyl Groups Studied by Soft X‐ray Spectroscopy and ab Initio Calculations

Author(s) -

Atak Kaan,

Engel Nicholas,

Lange Kathrin M.,

Golnak Ronny,

Gotz Malte,

Soldatov Mikhail,

Rubensson JanErik,

Kosugi Nobuhiro,

Aziz Emad F.

Publication year - 2012

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201200314

Subject(s) - chemistry , electrophile , nucleophile , atomic orbital , molecular orbital , computational chemistry , ab initio , phosphazene , sulfoxide , solvent effects , solvent , photochemistry , molecule , organic chemistry , physics , quantum mechanics , polymer , catalysis , electron

The polar character of the sulfinyl bond, which determines many of the properties of dimethyl sulfoxide (DMSO), is a result of charge transfer in low‐lying π‐type orbitals. This characteristic—together with the wide energy gap between the highest occupied and the lowest unoccupied molecular orbitals of this substance—makes DMSO a relatively inert aprotic solvent with strong nucleophilicity and electrophilicity.

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