Rapid Lithium Insertion and Location of Mobile Lithium in the Defect Perovskite Li 0.18 Sr 0.66 Ti 0.5 Nb 0.5 O 3 | Zendy

Brant William R. | Zendy; Schmid Siegbert | Zendy; Kuhn Alois | Zendy; Hester James | Zendy; Avdeev Maxim | Zendy; Sale Matthew | Zendy; Gu Qinfen | Zendy

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Rapid Lithium Insertion and Location of Mobile Lithium in the Defect Perovskite Li 0.18 Sr 0.66 Ti 0.5 Nb 0.5 O 3

Author(s) -

Brant William R.,

Schmid Siegbert,

Kuhn Alois,

Hester James,

Avdeev Maxim,

Sale Matthew,

Gu Qinfen

Publication year - 2012

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201200017

Subject(s) - lithium (medication) , electrochromism , perovskite (structure) , materials science , chemistry , crystallography , electrode , medicine , endocrinology

Fast and fancy: Lithium that was originally disordered within the structure of the perovskite Li 0.18 Sr 0.66 Ti 0.5 Nb 0.5 O 3 can be induced into ordering within the yellow region of the unit cell by low temperatures and treatment with n ‐butyl‐lithium. The fast kinetics of lithium insertion, in connection with a color change, make this nontoxic, air‐stable material a suitable candidate for use in electrochromic systems or lithium‐storage batteries.

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