Electrochemical Detection of the Thermally Induced Phase Transition of a Thin Stimuli‐Responsive Polymer Film | Zendy

Fandrich Artur | Zendy; Buller Jens | Zendy; Wischerhoff Erik | Zendy; Laschewsky André | Zendy; Lisdat Fred | Zendy

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Electrochemical Detection of the Thermally Induced Phase Transition of a Thin Stimuli‐Responsive Polymer Film

Author(s) -

Fandrich Artur,

Buller Jens,

Wischerhoff Erik,

Laschewsky André,

Lisdat Fred

Publication year - 2012

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201100924

Subject(s) - polymer , phase transition , electrochemistry , thin film , schematic , materials science , cyclic voltammetry , phase (matter) , phase change , chemical physics , transition metal , electrode , redox , nanotechnology , analytical chemistry (journal) , chemistry , organic chemistry , catalysis , condensed matter physics , thermodynamics , composite material , physics , electronic engineering , engineering , metallurgy

Quick and easy: An efficient approach for a direct observation of a thermally induced phase transition of a responsive polymer film on gold surfaces is described (see schematic). Voltammetric measurements show that the peak current and the peak separation for a small redox couple are particularly sensitive to the conformational change of the polymer film and allow its phase transition detection.

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