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Intercage Electron Transfer Driven by Electric Field in Robin–Day‐Type Molecules
Author(s) -
Wang YinFeng,
Li Ying,
Zhou ZhongJun,
Li ZhiRu,
Wu Di,
Huang Jiangen,
Gu Feng Long
Publication year - 2012
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201100790
Subject(s) - electron transfer , excited state , delocalized electron , chemistry , redox , ground state , electron , ion , molecule , electric field , crystallography , electron localization function , atomic physics , inorganic chemistry , physics , organic chemistry , quantum mechanics
A new class of isomers, namely, intercage electron‐transfer isomers, is reported for fluorinated double‐cage molecular anion e − @C 20 F 18 (NH) 2 C 20 F 18 with C 20 F 18 cages: 1 with the excess electron inside the left cage, 2 with the excess electron inside both cages, and 3 with the excess electron inside the right cage. Interestingly, the C 20 F 18 cages may be considered as two redox sites existing in a rare nonmetal mixed‐valent (0 and −1) molecular anion. The three isomers with two redox sites may be the founding members of a new class of mixed‐valent compounds, namely, nonmetal Robin–Day Class II with localized redox centers for 1 and 3 , and Class III with delocalized redox centers for 2 . Two intercage electron‐transfers pathways involving transfer of one or half an excess electron from one cage to the other are found: 1) Manipulating the external electric field (−0.001 a.u. for 1 → 3 and −0.0005 a.u. for 1 → 2 ) and 2) Exciting the transition from ground to first excited state and subsequent radiationless transition from the excited state to another ground state for 1 and 3 . For the exhibited microscopic electron‐transfer process 1 → 3 , 2 may be the transition state, and the electron‐transfer barrier of 6.021 kcal mol −1 is close to the electric field work of 8.04 kcal mol −1 .