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Prediction of a New Delocalised Bonding Motif between Group 15 or Group 16 Atoms
Author(s) -
Bühl Michael,
Kilian Petr,
Woollins J. Derek
Publication year - 2011
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201100423
Subject(s) - group (periodic table) , crystallography , chemistry , acceptor , molecule , motif (music) , computational chemistry , information retrieval , combinatorics , computer science , physics , organic chemistry , mathematics , condensed matter physics , acoustics
Fixed bonds: Using suitably constrained molecular scaffolds, electron delocalisation over four centers can be enforced in X‐E‐E‐X moieties (where E=group 15 or 16 element, X=acceptor, see picture). Identified through DFT calculations, a new facet of chemical bonding is waiting to be discovered.