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Quantitative Study of Non‐Covalent Interactions at the Electrode–Electrolyte Interface Using Cyanide‐Modified Pt(111) Electrodes
Author(s) -
EscuderoEscribano María,
Zoloff Michoff Martín E.,
Leiva Ezequiel P. M.,
Marković Nenad M.,
Gutiérrez Claudio,
Cuesta Ángel
Publication year - 2011
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201100327
Subject(s) - covalent bond , electrode , electrolyte , cyanide , electrochemistry , chemistry , helmholtz free energy , interface (matter) , nanotechnology , chemical physics , materials science , inorganic chemistry , molecule , organic chemistry , physics , thermodynamics , gibbs isotherm
Important interactions: Cations at the outer Helmholtz plane (OHP) can interact through non‐covalent interactions with species at the inner Helmholtz plane (IHP), which are covalently bonded to the electrode surface, thereby affecting the structure and the properties of the electrochemical double layer. These non‐covalent interactions can be studied quantitatively using cyanide‐modified Pt(111) electrodes (see picture).