Cation–π and Lone Pair–π Interactions Combined in One: The First Experimental Evidence of (H 3 O‐lp) + ⋅⋅⋅π‐System Binding in a Crystal | Zendy

Nelyubina Yulia V. | Zendy; Barzilovich Petro Yu. | Zendy; Antipin Mikhail Yu. | Zendy; Aldoshin Sergei M. | Zendy; Lyssenko Konstantin A. | Zendy

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Cation–π and Lone Pair–π Interactions Combined in One: The First Experimental Evidence of (H 3 O‐lp) + ⋅⋅⋅π‐System Binding in a Crystal

Author(s) -

Nelyubina Yulia V.,

Barzilovich Petro Yu.,

Antipin Mikhail Yu.,

Aldoshin Sergei M.,

Lyssenko Konstantin A.

Publication year - 2011

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201100294

Subject(s) - lone pair , supramolecular chemistry , oxonium ion , crystallography , chemistry , x ray crystallography , crystal (programming language) , crystal structure , diffraction , physics , computer science , molecule , ion , quantum mechanics , organic chemistry , programming language

A novel type of supramolecular interaction, with the two “antagonistic” binding models cation–π and lone pair–π fused into one, was found in a crystal of bis(oxonium) 4‐hydroxy‐1,3‐benzenedisulfonate by means of a topological analysis of the electron‐density distribution derived from high‐resolution X‐ray diffraction data.

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