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Insights into the Induced Ultrafast Electron Delocalization in Fe(CO) 5 Using Dark Channel Fluorescence Yield X‐Ray Absorption
Author(s) -
Bauer Matthias,
Stalinski Tom,
Aziz Emad F.
Publication year - 2011
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201100243
Subject(s) - delocalized electron , ultrashort pulse , femtosecond , yield (engineering) , absorption (acoustics) , fluorescence , electron , chemistry , analytical chemistry (journal) , chemical physics , nanotechnology , materials science , optics , physics , nuclear physics , organic chemistry , laser , metallurgy
Well‐coordinated: L 2,3 ‐edge X‐ray absorption measurements of Fe(CO) 5 , carried out for the first time in solution, are discussed (see picture). Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time‐scale yield new insights into the electronic structure.