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Comparative Study of Measured and Computed Raman Optical Activity of a Chiral Transition Metal Complex
Author(s) -
Johannessen Christian,
Hecht Lutz,
Merten Christian
Publication year - 2011
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201100128
Subject(s) - raman optical activity , raman spectroscopy , raman scattering , transition metal , metal , spectral line , enantiomer , chemistry , zirconium , yield (engineering) , analytical chemistry (journal) , chirality (physics) , scattering , materials science , stereochemistry , optics , inorganic chemistry , chiral symmetry , physics , organic chemistry , astronomy , metallurgy , catalysis , nambu–jona lasinio model , quantum mechanics , quark
On the ROA to somewhere: The first combined study of measured and computed Raman optical activity (ROA) of a transition metal complex under non‐resonant scattering conditions is reported. ROA measurements of the two enantiomers of the dichloro[ethylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)] zirconium(IV) complex yield virtually mirror‐image ROA spectra. The experimental spectra are directly comparable with predicted ROA spectra.