Infrared Spectra of Reactive Species Generated by Flash Pyrolysis in a Free Jet | Zendy

Fischer Kathrin H. | Zendy; Hemberger Patrick | Zendy; Fischer Ingo | Zendy; Rijs Anouk M. | Zendy

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Infrared Spectra of Reactive Species Generated by Flash Pyrolysis in a Free Jet

Author(s) -

Fischer Kathrin H.,

Hemberger Patrick,

Fischer Ingo,

Rijs Anouk M.

Publication year - 2010

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201000415

Subject(s) - infrared spectroscopy , pyrolysis , infrared , reactive intermediate , chemistry , diazirine , flash (photography) , carbene , spectral line , spectroscopy , photochemistry , analytical chemistry (journal) , organic chemistry , catalysis , physics , optics , quantum mechanics , astronomy

The infrared spectra of isolated reactive species in the gas phase are studied by IR/UV ion‐dip spectroscopy. The IR‐spectrum of the free allyl radical is observed. The pyrolysis of trifluoromethylphenyl diazirine yields, beside the corresponding carbene, trifluorostyrene as the major product (see figure).

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