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Infrared Spectra of Reactive Species Generated by Flash Pyrolysis in a Free Jet
Author(s) -
Fischer Kathrin H.,
Hemberger Patrick,
Fischer Ingo,
Rijs Anouk M.
Publication year - 2010
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201000415
Subject(s) - infrared spectroscopy , pyrolysis , infrared , reactive intermediate , chemistry , diazirine , flash (photography) , carbene , spectral line , spectroscopy , photochemistry , analytical chemistry (journal) , organic chemistry , catalysis , physics , optics , quantum mechanics , astronomy
The infrared spectra of isolated reactive species in the gas phase are studied by IR/UV ion‐dip spectroscopy. The IR‐spectrum of the free allyl radical is observed. The pyrolysis of trifluoromethylphenyl diazirine yields, beside the corresponding carbene, trifluorostyrene as the major product (see figure).