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Identification of Hydroperoxy Species as Reaction Intermediates in the Electrochemical Evolution of Oxygen on Gold
Author(s) -
Yeo Boon Siang,
Klaus Shan L.,
Ross Philip N.,
Mathies Richard A.,
Bell Alexis T.
Publication year - 2010
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201000294
Subject(s) - electrochemistry , oxygen evolution , raman spectroscopy , catalysis , chemistry , oxygen , identification (biology) , photochemistry , combinatorial chemistry , nanotechnology , organic chemistry , materials science , electrode , physics , biology , botany , optics
Gotcha! Using electrochemical surface‐enhanced Raman spectroscopy, surface‐bound hydroxyperoxy (AuOOH) is pinpointed in situ as a reaction intermediate of oxygen evolution on gold catalyst (see picture).
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