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Towards Molecular Temperature Programmers for Variable‐Temperature Kinetic Experiments
Author(s) -
Alibrandi Giuseppe,
Lister David G.,
Lo Vecchio Carmelo
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200900712
Subject(s) - kinetic energy , programmer , variable (mathematics) , activation energy , thermodynamics , thermal , acetic anhydride , chemistry , graph , materials science , chemical physics , computer science , organic chemistry , physics , mathematics , programming language , catalysis , theoretical computer science , mathematical analysis , quantum mechanics
A chemical device using a reaction of acetic anhydride as a source of thermal energy enabled the authors, without the need of a physical temperature programmer, to carry out a variable‐temperature kinetic experiment and obtain, in a single run, the activation parameters of a reaction (see graph).