Magnetic Alignment in Solid State and Temperature Hysteresis in Aqueous Tetrahydrofuran Solution for Tetrathiafulvaleno[18]annulenes | Zendy

Enozawa Hideo | Zendy; Hasegawa Masashi | Zendy; Isomura Eigo | Zendy; Nishinaga Tohru | Zendy; Kato Tadashi | Zendy; Yamato Masafumi | Zendy; Kimura Tsunehisa | Zendy; Iyoda Masahiko | Zendy

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Magnetic Alignment in Solid State and Temperature Hysteresis in Aqueous Tetrahydrofuran Solution for Tetrathiafulvaleno[18]annulenes

Author(s) -

Enozawa Hideo,

Hasegawa Masashi,

Isomura Eigo,

Nishinaga Tohru,

Kato Tadashi,

Yamato Masafumi,

Kimura Tsunehisa,

Iyoda Masahiko

Publication year - 2009

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200900545

Subject(s) - annulene , tetrahydrofuran , hysteresis , aqueous solution , chemistry , cluster (spacecraft) , octane , amphiphile , crystallography , organic chemistry , polymer , condensed matter physics , physics , copolymer , solvent , computer science , programming language

Tris(tetrathiafulvaleno)dodecadehydro[18]annulene‐hexaesters have a multi‐functionality that is very sensitive to small differences in the ester side‐chain. Self‐aggregation of the [18]annulenes in amphiphilic media such as THF–H 2 O (v/v, 1:1) either produce a fibrous structure or result in temperature hysteresis of the color and 1 H NMR signals. This temperature hysteresis in solution is due to both strong self‐aggregation behavior and unique cluster formation in a binary solution of THF and water.

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