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UV Polymerisation of Surfactants Adsorbed at the Nematic Liquid Crystal–Water Interface Produces an Optical Response
Author(s) -
Fletcher Paul D. I.,
Kang NaeGyu,
Paunov Vesselin N.
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200900405
Subject(s) - homeotropic alignment , liquid crystal , adsorption , polymerization , photochemistry , chemistry , chemical engineering , materials science , organic chemistry , polymer , optoelectronics , engineering
We have investigated the changes in crossed polariser optical textures produced by adsorption and UV polymerisation of a range of polymerisable surfactants at the interface between a nematic liquid crystal and water. Similar to non‐polymerisable surfactants, the adsorption of polymerisable surfactants with sufficiently long hydrophobic tail groups produces a transition from planar to homeotropic anchoring. UV polymerisation of surfactants with a polymerisable group located in the hydrophobic tail region changes the anchoring from homeotropic back to planar. Polymerisation in the hydrophilic headgroup region does not produce an optical transition. We demonstrate that these systems can be used to “write with light” in the interfaces and that they form the basis of a UV sensor device in which the optical response is visible to the naked eye.