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Robust Supramolecular Network on Ag(111): Hydrogen‐Bond Enhancement through Partial Alcohol Dehydrogenation
Author(s) -
Pawlak Remy,
Clair Sylvain,
Oison Vincent,
Abel Mathieu,
Ourdjini Oualid,
Zwaneveld Nikolas A. A.,
Gigmes Didier,
Bertin Denis,
y Laurent,
Porte Louis
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200900055
Subject(s) - dehydrogenation , supramolecular chemistry , nanoporous , hydrogen bond , chemistry , photochemistry , alcohol , alcohol oxidation , hydrogen , self assembly , catalysis , molecule , organic chemistry
Alcohol oxidation and self‐assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self‐assemblies, which evolve from a weakly bound dense phase to a strongly bound nanoporous open structure (see picture).