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Redox Properties of Mixed Lutetium/Yttrium Nitride Clusterfullerenes: Endohedral Lu x Y 3− x N@C 80 (I) ( x =0–3) Compounds
Author(s) -
Tarábek Ján,
Yang Shangfeng,
Dunsch Lothar
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200800811
Subject(s) - lutetium , cyclic voltammetry , yttrium , voltammetry , electron paramagnetic resonance , redox , analytical chemistry (journal) , chemistry , linear sweep voltammetry , materials science , inorganic chemistry , crystallography , electrochemistry , nuclear magnetic resonance , electrode , physics , organic chemistry , oxide , chromatography
The complex redox behavior of mixed lutetium/yttrium nitride clusterfullerenes of the series Lu x Y 3− x N§C 80 ( I h , x =0–3) (see figure) results in up to three irreversible reduction steps. A reduction mechanism is proposed based on fast‐scan and square‐wave voltammetry experiments combined with simulations of the voltammograms.The redox behavior of mixed lutetium/yttrium nitride clusterfullerenes of the series Lu x Y 3−x N@C 80 ( I h , x =0–3) is studied for the first time by means of cyclic voltammetry, fast‐scan cyclic voltammetry, square‐wave voltammetry, and electron paramagnetic resonance (EPR) spectroelectrochemistry. A reversible single‐electron‐transfer process, which does not result in an EPR signal, is detected during the anodic oxidation sweep of cyclic voltammetry experiments performed at different temperatures (296 and 360 K). The cathodic reduction sweep reveals a rather complex response for all the four clusterfullerenes—with up to three irreversible reduction steps. By correlating the results of fast‐scan and square‐wave voltammetry and combining them with simulations of the voltammograms, we are able to propose a reduction mechanism for the Lu x Y 3−x N@C 80 (I) ( x =0–3) fullerenes.