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Photoelectrochemical Studies of Gold Electrodes Chemically Modified with Single‐Walled Carbon Nanotubes
Author(s) -
Merli Daniele,
Profumo Antonella,
Dondi Daniele,
Albini Angelo
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200800684
Subject(s) - carbon nanotube , materials science , electrode , nanotechnology , electrochemistry , photoelectrochemistry , carbon fibers , photoelectrochemical cell , chemical engineering , chemistry , composite material , composite number , engineering , electrolyte
Seeing the light : An electrode is assembled by linking acid‐shortened single‐walled carbon nanotubes with carboxylic groups to a gold surface modified with a cysteamine monolayer. The electrode generates a photocurrent when illuminated with visible light in the presence of an electroactive species (see picture). With an appropriate applied potential the device behaves as a photodiode.The preparation, characterization and unique photoelectrochemical characteristics of a gold electrode chemically modified with suitably derivatized single‐walled carbon nanotubes (SWCNTs) are described. The SWCNT–chemically modified gold electrode (CNT‐CME) is assembled by linking acid‐shortened SWCNTs with carboxylic groups at the nanotube ends to a gold surface previously modified with a cysteamine monolayer. A persistent photocurrent is observed when the modified electrode is illuminated with visible light in the presence of an electroactive species (ascorbic acid, AsA). The influence of physical variables (applied potential, light intensity) and of chemical parameters (AsA concentration, pH) on the generated photocurrents is evaluated. With an appropriate applied potential this device behaves as a photodiode.