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Identification of Hydroxyl on Ni(111)
Author(s) -
Shan Junjun,
Kleyn Aart W.,
Juurlink Ludo B. F.
Publication year - 2009
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200800610
Subject(s) - dissociation (chemistry) , desorption , adsorption , chemistry , self ionization of water , oxygen , hydroxyl radical , hydrogen , electron energy loss spectroscopy , analytical chemistry (journal) , hydrogen bond , spectroscopy , annealing (glass) , thermal desorption spectroscopy , electron , crystallography , molecule , materials science , radical , organic chemistry , physics , quantum mechanics , composite material
Hydroxyl (OH) is identified and characterized on the Ni(111) surface by high‐resolution electron energy loss spectroscopy. We find clear evidence of stretching, bending, and translational modes that differ significantly from modes observed for H 2 O and O on Ni(111). Hydroxyl may be produced from water by two different methods. Annealing of water co‐adsorbed with atomic oxygen at 85 K to above 170 K leads to the formation of OH with simultaneous desorption of excess water. Pure water layers treated in the same fashion show no dissociation. However, the exposure of pure water to 20 eV electrons at temperatures below 120 K produces OH in the presence of adsorbed H 2 O. In combination with temperature‐programmed desorption studies, we show that the OH groups recombine between 180 and 240 K to form O and immediately desorbing H 2 O. The lack of influence of co‐adsorbed H 2 O at 85 K on the OH stretching mode indicates that OH does not participate in a hydrogen‐bonding network.