Ferrimagnetic Heisenberg Chains Derived From [M(CN) 8 ] 3−  (M=Mo V , W V ) Building‐Blocks | Zendy

Tanase Stefania | Zendy; de Jongh L. Jos. | Zendy; Prins Ferry | Zendy; Evangelisti Marco | Zendy

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Ferrimagnetic Heisenberg Chains Derived From [M(CN) 8 ] 3− (M=Mo V , W V ) Building‐Blocks

Author(s) -

Tanase Stefania,

de Jongh L. Jos.,

Prins Ferry,

Evangelisti Marco

Publication year - 2008

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200800345

Subject(s) - superexchange , ferrimagnetism , antiferromagnetism , chemistry , crystallography , magnetic susceptibility , condensed matter physics , heisenberg model , physics , materials science , magnetization , magnetic field , quantum mechanics

Antiferromagnetic superexchange: Two new 1D ferrimagnetic chains [Gd(pzam) 3 (H 2 O)M(CN) 8 ]⋅H 2 O (M V =Mo 1 , W 2 ) are synthesized and characterized; magnetic susceptibility data indicate antiferromagnetic superexchange between Gd III and M V via the cyanido bridge, and the occurrence of long‐range magnetic ordering between chains at T c ≈0.7 K in 1 (see figure).

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