Towards Near‐Infrared Chiroptically Switching Materials: Theoretical and Experimental Studies on Viologen‐Containing 1,1′‐Binaphthyls | Zendy

Deng Jian | Zendy; Song Naiheng | Zendy; Liu Wenjian | Zendy; Zhou Qifeng | Zendy; Wang Zhi Yuan | Zendy

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Towards Near‐Infrared Chiroptically Switching Materials: Theoretical and Experimental Studies on Viologen‐Containing 1,1′‐Binaphthyls

Author(s) -

Deng Jian,

Song Naiheng,

Liu Wenjian,

Zhou Qifeng,

Wang Zhi Yuan

Publication year - 2008

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200800140

Subject(s) - viologen , molecule , infrared , near infrared spectroscopy , chemistry , spectral properties , materials science , chemical physics , photochemistry , nanotechnology , computational chemistry , optics , organic chemistry , physics

NIR chiroptical switching: The first demonstration of significant chiroptical switching in the NIR spectral region of 700–2000 nm (see figure) is made with novel redox‐active chiral molecules. These are designed according to a newly established unambiguous structural model correlating chiroptical properties with geometric structures.

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