Density‐Independent Contributions to Longitudinal Relaxation in  83 Kr | Zendy

Cleveland Zackary I. | Zendy; Meersmann Thomas | Zendy

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Density‐Independent Contributions to Longitudinal Relaxation in 83 Kr

Author(s) -

Cleveland Zackary I.,

Meersmann Thomas

Publication year - 2008

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200800134

Subject(s) - relaxation (psychology) , van der waals force , chemistry , van der waals radius , composition (language) , gas phase , chemical physics , thermodynamics , molecule , physics , organic chemistry , psychology , social psychology , linguistics , philosophy

Gas‐phase relaxation: 83 Kr longitudinal relaxation is studied as a function of gas composition and surface chemistry. Two density‐independent relaxation mechanisms are identified. One results from surface interactions and is composition‐independent and the other from the formation of Kr 2 van der Waals dimers and depends strongly on composition.

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