Direct Probe of NO Vibration in the Naked Ferric Heme Nitrosyl Complex | Zendy

Chiavarino Barbara | Zendy; Crestoni Maria Elisa | Zendy; Fornarini Simonetta | Zendy; Lanucara Francesco | Zendy; Lemaire Joel | Zendy; Maître Philippe | Zendy; Scuderi Debora | Zendy

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Direct Probe of NO Vibration in the Naked Ferric Heme Nitrosyl Complex

Author(s) -

Chiavarino Barbara,

Crestoni Maria Elisa,

Fornarini Simonetta,

Lanucara Francesco,

Lemaire Joel,

Maître Philippe,

Scuderi Debora

Publication year - 2008

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200800086

Subject(s) - porphyrin , dissociation (chemistry) , ferric , chemistry , photochemistry , heme , vibration , mass spectrometry , molecular vibration , nitric oxide , infrared spectroscopy , spectrometer , analytical chemistry (journal) , inorganic chemistry , molecule , optics , physics , organic chemistry , quantum mechanics , chromatography , enzyme

Vibrational features: The coupling of a free electron laser to a mass spectrometer measures the IR spectrum of iron porphyrin complexes of nitric oxide (see figure). Comparison of the photo‐dissociation spectra, identifies the NO vibration at 1842 cm −1 .

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