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Mechanism of Thermal Toluene Autoxidation
Author(s) -
Hermans Ive,
Peeters Jozef,
Vereecken Luc,
Jacobs Pierre A.
Publication year - 2007
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200700563
Subject(s) - benzaldehyde , benzyl alcohol , chemistry , radical , toluene , autoxidation , photochemistry , benzoic acid , chain propagation , chain reaction , hydrogen peroxide , reactivity (psychology) , chain termination , alcohol , medicinal chemistry , organic chemistry , catalysis , monomer , medicine , alternative medicine , pathology , polymer , radical polymerization
Aerobic oxidation of toluene (PhCH 3 ) is investigated by complementary experimental and theoretical methodologies. Whereas the reaction of the chain‐carrying benzylperoxyl radicals with the substrate produces predominantly benzyl hydroperoxide, benzyl alcohol and benzaldehyde originate mainly from subsequent propagation of the hydroperoxide product. Nevertheless, a significant fraction of benzaldehyde is also produced in primary PhCH 3 propagation, presumably via proton rather than hydrogen transfer. An equimolar amount of benzyl alcohol, together with benzoic acid, is additionally produced in the tertiary propagation of PhCHO with benzylperoxyl radicals. The “hot” oxy radicals generated in this step can also abstract aromatic hydrogen atoms from PhCH 3 , and this results in production of cresols, known inhibitors of radical‐chain reactions. The very fast benzyl peroxyl‐initiated co‐oxidation of benzyl alcohol generates HO 2 . radicals, along with benzaldehyde. This reaction also causes a decrease in the overall oxidation rate, due to the fast chain‐terminating reaction of HO 2 . with the benzylperoxyl radicals, which causes a loss of chain carriers. Moreover, due to the fast equilibrium PhCH 2 OOH+HO 2 . ⇌PhCH 2 OO . +H 2 O 2 , and the much lower reactivity of H 2 O 2 compared to PhCH 2 OOH, the fast co‐oxidation of the alcohol means that HO 2 . gradually takes over the role of benzylperoxyl as principal chain carrier. This drastically changes the autoxidation mechanism and, among other things, causes a sharp decrease in the hydroperoxide yield.