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2D Supramolecular Self‐Assembly of Binary Organic Monolayers
Author(s) -
Barrena Esther,
de Oteyza Dimas G.,
Dosch Helmut,
Wakayama Yutaka
Publication year - 2007
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200700494
Subject(s) - monolayer , supramolecular chemistry , phase diagram , binary number , organic molecules , molecule , evaporation , chemistry , self assembly , order (exchange) , crystallography , nanotechnology , phase (matter) , materials science , physics , organic chemistry , thermodynamics , arithmetic , mathematics , finance , economics
Self organisation : 2D binary molecular monolayers formed by co‐evaporation of two small organic molecules (DIP and F 16 CuPc), achieve exceptional order through CF⋅⋅⋅H interactions. Room temperature STM images of the “2D phase diagram” for binary structures versus the relative coverage on Au(111) and Cu(111) are shown in the figure.