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Chiral Transformation of Achiral J‐aggregates of a Cyanine Dye Templated by Human Serum Albumin
Author(s) -
Zhang Yazhou,
Xiang Junfeng,
Tang Yalin,
Xu Guangzhi,
Yan Wenpeng
Publication year - 2007
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200600548
Subject(s) - cyanine , circular dichroism , chirality (physics) , human serum albumin , chemistry , phosphate buffered saline , j aggregate , transformation (genetics) , stereochemistry , chromatography , organic chemistry , molecule , biochemistry , optics , physics , nambu–jona lasinio model , chiral symmetry breaking , fluorescence , gene , quark , quantum mechanics
Double‐minded supramolecules : The interactions between human serum albumin (HSA) and J‐aggregation of a cyanine dye (PTC) in phosphate buffer solution are studied. In the presence of HSA, the achiral J‐aggregate shows chirality. The chirality can be inversed by adjusting the ratio of HSA to PTC and the pH value (see picture; CD=circular dichroism).

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