Can a Blue Shift of the CH Stretching Modes of Inactivated C Groups be an Indicator of Weak CH⋅⋅⋅O Hydrogen Bonds? | Zendy

Xu Zheng | Zendy; Li Haoran | Zendy; Wang Congmin | Zendy

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Can a Blue Shift of the CH Stretching Modes of Inactivated C Groups be an Indicator of Weak CH⋅⋅⋅O Hydrogen Bonds?

Author(s) -

Xu Zheng,

Li Haoran,

Wang Congmin

Publication year - 2006

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200600486

Subject(s) - hydrogen bond , blueshift , chemistry , methylene blue , acetone , nitrogen , photochemistry , hydrogen , methylene , stereochemistry , crystallography , medicinal chemistry , molecule , organic chemistry , materials science , photoluminescence , catalysis , optoelectronics , photocatalysis

Anyone for TEA? By means of a combined spectroscopic and theoretical study of TEA–[D 6 ]acetone, TEA–CCl 4 , and TEA–CDCl 3 mixtures, the hydrogen bonds formed at the nitrogen site are found to play an important role in the blue shift of the stretching modes of the methylene bond, υ C−H (see figure).

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