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Excitation of the Asymmetric Stretch Vibration of CO 2 in OH+CO→H+CO 2 Reaction
Author(s) -
Shi Congyun,
Ren Li,
Kong Fanao
Publication year - 2006
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200500695
Subject(s) - excitation , fourier transform infrared spectroscopy , fourier transform , infrared , chemistry , analytical chemistry (journal) , infrared spectroscopy , molecular vibration , spectroscopy , product (mathematics) , molecule , physics , optics , organic chemistry , quantum mechanics , geometry , mathematics
CO 2 vibrations: High excitation in the asymmetric stretch ( v 3 ) mode of the CO 2 product in the OH+CO reaction has been found (see picture). The strong IR emission was detected by time‐resolved Fourier transform infrared (TR‐FTIR) emission spectroscopy. The observed vibrational distribution is used for comparison with a variety of theoretical calculations on this reaction.