Excitation of the Asymmetric Stretch Vibration of CO 2  in OH+CO→H+CO 2  Reaction | Zendy

Shi Congyun | Zendy; Ren Li | Zendy; Kong Fanao | Zendy

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Excitation of the Asymmetric Stretch Vibration of CO 2 in OH+CO→H+CO 2 Reaction

Author(s) -

Shi Congyun,

Ren Li,

Kong Fanao

Publication year - 2006

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200500695

Subject(s) - excitation , fourier transform infrared spectroscopy , fourier transform , infrared , chemistry , analytical chemistry (journal) , infrared spectroscopy , molecular vibration , spectroscopy , product (mathematics) , molecule , physics , optics , organic chemistry , quantum mechanics , geometry , mathematics

CO 2 vibrations: High excitation in the asymmetric stretch ( v 3 ) mode of the CO 2 product in the OH+CO reaction has been found (see picture). The strong IR emission was detected by time‐resolved Fourier transform infrared (TR‐FTIR) emission spectroscopy. The observed vibrational distribution is used for comparison with a variety of theoretical calculations on this reaction.

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