Adsorption Isotherms of  ortho ‐ and  para ‐Water | Zendy

Tikhonov Vladimir I. | Zendy; Volkov Alexander A. | Zendy

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Adsorption Isotherms of ortho ‐ and para ‐Water

Author(s) -

Tikhonov Vladimir I.,

Volkov Alexander A.

Publication year - 2006

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200500627

Subject(s) - adsorption , chemistry , thermodynamics , component (thermodynamics) , molecule , phase (matter) , volume (thermodynamics) , chromatography , organic chemistry , physics

Spin‐modifyied water : Adsorption isotherms are measured separately for ortho ‐ and para ‐water on a hydrophobic adsorbent (see picture; adsorbed molecules n O and n P as functions of partial pressures p O and p P ) . In a closed volume filled with adsorbent the equilibrium gas‐phase ortho : para ratio deviates noticeably from the statistical 3:1 in favor of the ortho component. Correspondingly, adsorbed water is formally para ‐enriched.

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