A C 2  Molecule Entrapped in the Pentagonal‐Dodecahedral Y 2  Cage in Y 2 C 2 @C 82 (III) | Zendy

Nishibori Eiji | Zendy; Narioka Shintaro | Zendy; Takata Masaki | Zendy; Sakata Makoto | Zendy; Inoue Takashi | Zendy; Shinohara Hisanori | Zendy

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A C 2 Molecule Entrapped in the Pentagonal‐Dodecahedral Y 2 Cage in Y 2 C 2 @C 82 (III)

Author(s) -

Nishibori Eiji,

Narioka Shintaro,

Takata Masaki,

Sakata Makoto,

Inoue Takashi,

Shinohara Hisanori

Publication year - 2006

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200500437

Subject(s) - dodecahedron , crystallography , molecule , cage , synchrotron , rietveld refinement , x ray crystallography , chemistry , materials science , crystal structure , diffraction , physics , mathematics , organic chemistry , combinatorics , nuclear physics , optics

Carbon‐encapsulating metallofullerenes: A C 2 molecule is entrapped in the pentagonal‐dodecahedral charge density of Y 2 in Y 2 C 2 @C 82 (III) according to the maximum entropy/Rietveld analysis of the synchrotron X‐ray powder diffraction data, which clearly show an additional charge‐density peak for C 2 (blue) inside the pentagonal‐dodecahedral Y 2 cage (red) in Y 2 C 2 @C 82 (III) (picture, left) but not in Y 2 @C 82 (III) (right).

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