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Asbestos Mineral Analysis by UV Raman and Energy‐Dispersive X‐ray Spectroscopy
Author(s) -
Petry Renate,
Mastalerz Remigius,
Zahn Stefan,
Mayerhöfer Thomas G.,
Völksch Günther,
ViereckGötte Lothar,
KreherHartmann Birgit,
Holz Lothar,
Lankers Markus,
Popp Jürgen
Publication year - 2006
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200500303
Subject(s) - tremolite , raman spectroscopy , actinolite , asbestos , chrysotile , analytical chemistry (journal) , chemistry , mineral , spectroscopy , mineralogy , materials science , optics , environmental chemistry , quartz , metallurgy , physics , epidote , organic chemistry , quantum mechanics , chlorite
10.1002/cphc.200500303.abs The applicability of a UV micro‐Raman setup was assessed for the rapid identification of fibrous asbestos minerals using 257 and 244 nm laser light for excitation. Raman spectra were obtained from six asbestos reference standards belonging to two basic structural groups: the serpentines (chrysotile) and the amphiboles (crocidolite, tremolite, amosite, anthophyllite, and actinolite). The UV Raman spectra reported here for the first time are free from fluorescence, which is especially helpful in assessing the hydroxyl‐stretching vibrations. The spectra exhibit sharp bands characteristic of each asbestos species, which can be used for the unambiguous identification of known and unknown asbestos fibres. Evident changes of the relative band intensities sensitively reflect the chemical substitutions that typically occur in asbestos minerals. The elemental composition of the asbestos reference samples was analysed by using a scanning electron microscope equipped with an energy‐dispersive X‐ray (EDX) spectrometer. The discussion of the experimental results in terms of EDX analysis sheds new light on the structural and vibrational consequences of cation distribution in asbestos minerals.