Mechanisms of Direct and TiO 2 ‐Photocatalysed UV Degradation of Phenylurea Herbicides | Zendy

Canle López Moisés | Zendy; Fernández M. Isabel | Zendy; Rodríguez Santiago | Zendy; Santaballa J. Arturo | Zendy; Steenken Steen | Zendy; Vulliet Emmanuelle | Zendy

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Mechanisms of Direct and TiO 2 ‐Photocatalysed UV Degradation of Phenylurea Herbicides

Author(s) -

Canle López Moisés,

Fernández M. Isabel,

Rodríguez Santiago,

Santaballa J. Arturo,

Steenken Steen,

Vulliet Emmanuelle

Publication year - 2005

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200500004

Subject(s) - photocatalysis , chemistry , reactivity (psychology) , photodegradation , photochemistry , radiolysis , radical , medicinal chemistry , quantum yield , reaction rate constant , redox , catalysis , inorganic chemistry , organic chemistry , kinetics , medicine , physics , alternative medicine , pathology , quantum mechanics , fluorescence

Phenylurea herbicides undergo low‐yield ( ϕ PI <15 %) monophotonic photoionisation upon 193‐nm laser flash excitation. The so‐formed radical cations (phenylurea . + ) are highly acidic (−1.5

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