Infrared Spectroscopy of Protonated Phenylsilane in the Gas Phase | Zendy

Chiavarino Barbara | Zendy; Crestoni Maria E. | Zendy; Fornarini Simonetta | Zendy; Lemaire Joël | Zendy; Aleese Luke Mac | Zendy; Maître Philippe | Zendy

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Infrared Spectroscopy of Protonated Phenylsilane in the Gas Phase

Author(s) -

Chiavarino Barbara,

Crestoni Maria E.,

Fornarini Simonetta,

Lemaire Joël,

Aleese Luke Mac,

Maître Philippe

Publication year - 2005

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.200400511

Subject(s) - infrared multiphoton dissociation , protonation , infrared spectroscopy , dissociation (chemistry) , chemistry , spectroscopy , ion , photochemistry , phenylsilane , gas phase , infrared , mass spectrometry , absorption spectroscopy , analytical chemistry (journal) , organic chemistry , catalysis , optics , physics , chromatography , quantum mechanics

Gaseous ions: A variant of IR spectroscopy, developed to solve the structure of gaseous ions, was applied to the prototypical silyl‐substituted arenium ion, [H 3 SiC 6 H 6 ] + . The experimental IR multiphoton‐induced dissociation (IRMPD) spectrum is found to match the IR absorption features calculated for the ipso ‐protonated species (see figure).

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