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Bifurcated CH 2 ⋅⋅⋅O and (CH) 2 ⋅⋅⋅FC Weak Hydrogen Bonds: The Oxirane–Difluoromethane Complex
Author(s) -
Blanco Susana,
López Juan C.,
Lesarri Alberto,
Caminati Walther,
Alonso José L.
Publication year - 2004
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200400360
Subject(s) - difluoromethane , hydrogen bond , chemistry , hydrogen , supersonic speed , computational chemistry , crystallography , molecule , thermodynamics , physics , refrigerant , organic chemistry , gas compressor
Bifurcated hydrogen bonds: The oxirane–difluoromethane molecular complex, generated in a supersonic jet, is stabilized by two bifurcated weak hydrogen bonds (see picture). The binding energy of the complex was estimated to be 9.6 kJ mol −1 .