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The Potential of the Xenon “Spin‐Spy” Methodology for the Study of Configurational Equilibria in Solution
Author(s) -
Locci Emanuela,
Reisse Jacques,
Bartik Kristin
Publication year - 2003
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200390051
Subject(s) - xenon , mutarotation , chemistry , isotopes of xenon , nuclear magnetic resonance spectroscopy , spectroscopy , computational chemistry , analytical chemistry (journal) , chemical physics , nuclear magnetic resonance , stereochemistry , organic chemistry , physics , quantum mechanics
Xenon, a gas of rare ability: The mutarotation of D ‐glucose (see structure) was monitored using 129 Xe NMR spectroscopy. This is the first example of the use of xenon NMR spectroscopy to probe a configurational equilibrium in solution of a system which does not complex xenon.