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Concerted Two‐Electron‐Transfer Processes in Mixed‐Valence Species with Square Topology
Author(s) -
Lambert Christoph
Publication year - 2003
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.200300726
Subject(s) - topology (electrical circuits) , electron transfer , chemical physics , valence (chemistry) , electron , square (algebra) , electronic structure , chemistry , ground state , atomic physics , computational chemistry , molecular physics , physics , quantum mechanics , photochemistry , mathematics , geometry , combinatorics
Electronic chequers : Mixed‐valent species were examined theoretically. The topology of the ground‐state potential‐energy surface of square mixed‐valent derivatives (see picture) can be controlled and, in this way, the choice of a concerted two‐electron transfer or consecutive single‐electron transfer may also be made.
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