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Anchoring CuO Nanoparticles On C, N‐Codoped G‐ C 3 N 4 Nanosheets from Melamine‐Entrapped MOF Gel for High‐Efficiency Oxygen Evolution
Author(s) -
Zhao Lu,
Kuang Xuan,
Liu Zhaoxuan,
Hou Ying,
Wang Zhiling,
Wei Qin,
Lee Jin Yong,
Kang Baotao
Publication year - 2019
Publication title -
chemnanomat
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.947
H-Index - 32
ISSN - 2199-692X
DOI - 10.1002/cnma.201900249
Subject(s) - overpotential , materials science , nanoparticle , melamine , graphitic carbon nitride , pyrolysis , chemical engineering , oxide , carbon fibers , oxygen evolution , electrode , nanotechnology , catalysis , electrochemistry , chemistry , organic chemistry , composite material , metallurgy , photocatalysis , composite number , engineering
Facile engineering of transitional metal oxide nanoparticles (NPs) homogeneously anchored on graphitic carbon nitride ( g ‐C 3 N 4 ) is very important. Herein, we develop a rapid and facile route to synthesize CuO NPs‐ and C, N‐codoped g ‐C 3 N 4 nanosheets grown on Ni foil (CuO/CN−C 3 N 4 /Ni‐f), derived from the oxidation‐pyrolysis of melamine‐entrapped Cu(II)‐MOF gel in the air. A detailed growth process for the hierarchical structure is studied. The obtained hierarchical structure without any binders used directly as an electrode only needs an overpotential of 223 mV to achieve a current density of 50 mA cm −2 in 0.5 M KOH, implying its highly efficient electrocatalytic activity. Notably, this material also exhibits strong long‐term durability. Free energy calculations show that the intrinsic origin of the outstanding activity is derived from sufficient exposure of active sites for CuO NPs anchored on the nanosheets and high N content.