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Intelligent Optimization of Na−Mn−W/SiO 2 Catalysts for the Oxidative Coupling of Methane
Author(s) -
Li Zhinian,
Wang Shenliang,
Hong Wei,
Zou Shihui,
Xiao Liping,
Fan Jie
Publication year - 2018
Publication title -
chemnanomat
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.947
H-Index - 32
ISSN - 2199-692X
DOI - 10.1002/cnma.201800019
Subject(s) - catalysis , oxidative coupling of methane , space velocity , oxide , metal , methane , chemistry , homogeneous , materials science , inorganic chemistry , chemical engineering , selectivity , organic chemistry , physics , thermodynamics , engineering
Optimizing the performance and understanding the mechanism of metal oxide catalysts in the oxidative coupling of methane (OCM) is one of the most important projects in industrial catalysis. Here, we report an intelligent approach to screen Na−Mn−W/SiO 2 catalysts for the OCM reaction via ink‐jet printing and multidimensional group testing. The ink‐jet‐printing‐assisted (IJP‐A) synthetic methodology ensured a fast synthesis of 1536 catalysts that were evaluated in 24 tests via a multidimensional group testing strategy (m‐GT). After two‐round synthesis‐and‐screening processes, several excellent groups with different composition space were screened out. Among the excellent catalysts, the OCM performance of Na−Mn−W/SiO 2 catalyst with higher Na, Mn and W content (G3 and G7) was less sensitive to its constituent than that of Na−Mn−W/SiO 2 catalyst with lower Na, Mn and W content (G1). These results indicated the sensitivity of performance to its Na, Mn and W content decreased in larger Na, Mn and W spaces, consistent with the complex homogeneous/heterogeneous reaction mechanism and multi‐active sites. A series of Na−Mn−W/SiO 2 formulas with good performance also provide a reasonable explanation to its excellent stability for the OCM reaction. In addition, this intelligent optimization in total space offers a pathway to study the multicomponent metal oxide catalyst in the OCM reaction.