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Enhanced Performance of a Pillared TiO 2 Nanohybrid as an Anode Material for Fast and Reversible Lithium Storage
Author(s) -
Wang Bei,
Bai Yang,
Xing Zheng,
HulicovaJurcakova Denisa,
Wang Lianzhou
Publication year - 2015
Publication title -
chemnanomat
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.947
H-Index - 32
ISSN - 2199-692X
DOI - 10.1002/cnma.201500002
Subject(s) - materials science , calcination , lithium (medication) , exfoliation joint , anode , chemical engineering , nanoparticle , intercalation (chemistry) , nanostructure , electrochemistry , diffusion , nanocomposite , nanotechnology , inorganic chemistry , graphene , chemistry , electrode , organic chemistry , medicine , physics , engineering , endocrinology , thermodynamics , catalysis
TiO 2 nanohybrid material with pillared nanostructure is prepared via an exfoliation/reassembly process of exfoliated Ti 0.91 O 2 nanosheets and TiO 2 nanoparticles, followed by a calcination treatment. The as‐prepared material consists of TiO 2 nanoparticles (≈5–8 nm) randomly distributed in the interlayers of reassembled TiO 2 nanosheets, resulting in a high specific surface area of 207 m 2 g −1 , which can effectively facilitate lithium diffusion and accommodation. The formed disordered TiO 2 pillared material can deliver a specific discharge capacity of 349 mA h g −1 at 0.2 C with sufficient lithium intercalation and exceptional cycling stability for up to 150 cycles, and survive more than 350 continuous cycles with almost no capacity fading at 1 C, 5 C and 10 C. The superior electrochemical properties of our TiO 2 nanohybrids demonstrate sufficient and reversible lithium insertion/extraction, and ultrafast lithium diffusion and storage capabilities.